DKIM (DomainKeys Identified Mail) attaches a tamper-evident digital signature to every email you send. Recipient servers check the signature against a public key in your DNS. If it matches, the message is genuinely from you and hasn't been altered in transit.
Where SPF uses a DNS TXT record to publish the list of servers allowed to send for you, DKIM adds a cryptographic signature to the header of each outgoing message. The recipient server reads the signature, looks up the public key in your DNS, and checks the match. DKIM is effectively a check of "I am who I say I am" for each individual message.
Like SPF, DKIM alone doesn't guarantee inbox placement. But without it, most mailbox providers assume Act-On isn't authorised to send for your domain, and messages get filtered to spam or rejected.
Where DKIM gets configured in Act-On
DKIM is part of Email From Setup. You publish a CNAME record in DNS that points to Act-On's signing infrastructure. For step-by-step instructions across the common DNS providers (Cloudflare, GoDaddy, Bluehost, HostGator, Network Solutions), see Editing Your DNS to Implement DKIM.